Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 22, Pages 8525-8527Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja202818v
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Funding
- NSF CRIF [CHE-0639094]
- National Institutes of Health [NIH 5R01GM031332-27]
- Mitsui Chemicals, Inc.
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0809418] Funding Source: National Science Foundation
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We report the development of ruthenium-based metathesis catalysts with chelating N-heterocyclic carbene (NHC) ligands that catalyze highly Z-selective olefin metathesis. A very simple and convenient procedure for the synthesis of such catalysts has been developed. Intramolecular C-H bond activation of the NHC ligand, promoted by anion ligand substitution, forms the appropriate chelate for stereocontrolled olefin metathesis.
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