Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 49, Pages 19646-19649Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja208495u
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Funding
- World Class University (WCU) [R33-2008-000-10003]
- Priority Research Centers through National Research Foundation of Korea [2009-0093818]
- Ministry of Education, Science and Technology
- NIH [GM-57052]
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A novel, interlocked, self-assembled (M2L2)(2) molecular architecture was constructed from an arene-Ru acceptor and a 1,4-di(pyridin-4-yl)buta-1,3-diyne donor. Two M2L2 units, with cavities of similar to 7.21 angstrom, spontaneously interlock, with one unit encapsulating a twin in a non-catenane fashion. The dimeric host guest complex thus formed is unique among two-dimensional self-assemblies and is stabilized by pi-pi interactions between the M2L2 units.
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