Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 2, Pages 878-881Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja210614y
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Funding
- 973 Program of China [973-2009CB825300]
- NSFC [20872155, 20972175, 20923005]
- STCSM [11JC1415000]
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A palladium-catalyzed intramolecular oxidative aryltrifluoromethylation reaction of activated alkenes has been explored. The reaction allows for an efficient synthesis of a variety of CF3-containing oxindoles. Preliminary mechanistic study indicated that the reaction involves a C-sp(3)-Pd-IV(CF3) intermediate, which undergoes reductive elimination to afford a C-sp(3)-CF3 bond.
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