4.8 Article

Single-Molecule Chemistry and Analysis: Mode-Specific Dehydrogenation of Adsorbed Propene by Inelastic Electron Tunneling

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 15, Pages 5689-5691

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja200143z

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Funding

  1. Swiss Secretary for Education and Research (SER)
  2. Swiss National Science Foundation (SNSF)

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A single propene molecule, located in the junction between the tip of a scanning tunneling microscope (STM) and a Cu(211) surface can be dehydrogenated by inelastic electron tunneling. This reaction requires excitation of the asymmetric C-H stretching vibration of the =CH2 group. The product is then identified by inelastic electron tunneling action spectroscopy (IETAS).

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