Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 23, Pages 8874-8876Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja203208t
Keywords
-
Categories
Funding
- National Science Foundation [CHE-0953484, CHE-0608142, CHE-0749868, CHE-0716718]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1054286, 0953484] Funding Source: National Science Foundation
Ask authors/readers for more resources
Reaction of carbene-stabilized disilicon L: Si=Si:L (L: = :C{N(2,6-(Pr2C6H3)-C-1)CH}(2), 1) with BH3 center dot THF results in facile cleavage of the silicon-silicon double bond and the formation of two quite different, Push-pull stabilized products with borane- and carbene-coordinated silylene moieties: 2, containing a parent silylene (:SiH2); and 3, containing a unique three-membered cyclosilylene.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
