Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 2, Pages 924-927Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja209643b
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- King Abdullah University of Science and Technology (KAUST) [FIC/2010/06]
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Reaction of biphenyl-3,4',5-tricarboxylate (H3BPT) and CdCl2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd-6(BPT)(4)Cl-4(H2O)(4)]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.
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