Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 20, Pages 7624-7627Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja110685k
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- Alexander-von-Humboldt Foundation
- Hessian Ministry of Science and Arts (HMWK)
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We present a new class of catalysts based on the combination of N,N'-diaryl(thio)ureas and weak silicon Lewis acids (e.g., SiCl(4)). Such silicon-(thio)urea catalysts effectively catalyze the stereospecific rearrangement of epoxides to quaternary carbaldehydes.
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