4.8 Article

d-f Heterobimetallic Association between Ytterbium and Ruthenium Carbon-Rich Complexes: Redox Commutation of Near-IR Luminescence

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 16, Pages 6174-6176

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja2023515

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Funding

  1. Universite de Rennes 1
  2. CNRS
  3. ANR [ANR-09-JCJC-0025]
  4. Region Bretagne
  5. Agence Nationale de la Recherche (ANR) [ANR-09-JCJC-0025] Funding Source: Agence Nationale de la Recherche (ANR)

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We describe how the association between an ytterbium ion and a ruthenium carbon-rich complex enables the first switching of the near-IR Yb(III) luminescence by taking advantage of the redox commutation of the carbon-rich antenna.

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