Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 33, Pages 12937-12939Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja204426s
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- Nissan Chemical Industries, Ltd.
- MEXT, Japan
- JSPS
- Grants-in-Aid for Scientific Research [11J03551] Funding Source: KAKEN
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The first general method for iron-catalyzed aerobic oxidative kinetic resolution of secondary alcohols was achieved with good to high enantiomeric differentiation (k(rel) = 7-50). Although iron(salan) complex 1 does not catalyze alcohol oxidation, the naphthoxide-bound iron(salan) complex does.
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