Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 7, Pages 2112-2115Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja110634h
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- Deutsche Forschungsgemeinschaft [SFB 858, IRTG 1444]
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The oxidative addition of 2-chloro-N-methylbenzimdazole to complexes of type [M(PPh3)(4)] yields after N-protonation compounds with NH,NMe-substituted NHC ligands. For M = Pd complex compound trans-[3]BF4 was obtained, while the oxidative addition for M = Pt yielded a mixture of cis-[4]BF4 (major) and trans-[4]BF4 (minor).
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