Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 30, Pages 11450-11453Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja203645m
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Funding
- National Science Foundation [DMR-0812337, DMR-0705015, DMR-0821313, CHE-1012636, DMR-0906898]
- Ohio Board of Regents
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0821313] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1012636] Funding Source: National Science Foundation
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An approach to multicomponent coordination-driven self-assembly of the first terpyridine-based, shape-persistent, giant two-dimensional D-6h supramacromolecular spoked wheel is reported. Mixing core T6, rim T3, and Zn-II or Cd-II ions in a stoichiometric ratio (1:6:12) permitted the selective generation of a highly symmetric spoked wheel in 94% isolated yield via geometric and thermodynamic control. The products were characterized by a combination of traveling-wave ion mobility mass spectrometry and NMR techniques together with TEM imaging, which agreed with computational simulations.
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