Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 2, Pages 170-171Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1089217
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- Specially Promoted Research [18002011]
- Global COE
- Ministry of Education, Science, and Culture, Japan
- JSPS
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Ir(salen) complexes were found to catalyze enantioselective cyclopropenation efficiently. Cyclopropenation can be carried out using either a donor/acceptor- or an acceptor/acceptor-substituted diazo compound such as alpha-aryl-alpha-diazoacetates, alpha-phenyl-alpha-diazophosphonate, 2,2,2-trifluoro-1-phenyl-1-diazoethane, and alpha-cyano-alpha-diazoacetamide as carbenoid precursors. The reactions provide highly enantioenriched cyclopropenes (84-98% ee) with a functionalized quaternary carbon as versatile building blocks.
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