Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 11, Pages 3820-3823Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja200346a
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Funding
- U.S. National Science Foundation through Center for Chemical Innovation [CHE-0802907]
- Brandeis University [CHE-0521047]
- Schiff Fellowship
- LSAMP BTD Fellowship
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0802907] Funding Source: National Science Foundation
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The Pd(I)-Pd(I) dimer [((PNP)-P-F)Pd-](2) reacts with O-2 upon exposure to light to produce either the superoxide ((PNP)-P-F)PdO2 or the peroxide [((PNP)-P-F)PdO-] 2, which exist in equilibrium with free O-2. Both complexes contain square-planar Pd(II) centers. The unpaired electron density in ((PNP)-P-F)PdO2 is localized on the superoxide ligand.
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