4.8 Article

Heterolytic Dissociation of Water Demonstrated by Crystal-to-Crystal Core Interconversion from (μ-Oxo)divanadium to Bis(μ-hydroxo)divanadium Substituted Polyoxometalates

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 6, Pages 1622-1625

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja108245g

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Funding

  1. Japan Science and Technology Agency (JST)
  2. Ministry of Education, Culture, Science, Sports and Technology of Japan (MEXT)
  3. Japan Society for the Promotion of Science (JSPS)

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The heterolytic dissociation of water with the previously unknown four-coordinated syn-linear (mu-oxo)divanadium core to form the five-coordinated bis(mu-hydroxo)divanadium core was confirmed by a crystal-to-crystal transformation.

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