Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 18, Pages 6918-6921Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja201337x
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Funding
- MEXT, Japan [20675002, 23105512]
- Grants-in-Aid for Scientific Research [23310051, 20675002] Funding Source: KAKEN
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It has been established that a cationic rhodium(I)/(R)-H-8-BINAP or (R)-Segphos complex catalyzes two modes of enantioselective cyclizations of gamma-alkynylaldehydes with acyl phosphonates via C-P or C-H bond cleavage. The ligands of the Rh(I) complexes and the substitutents of both gamma-alkynylaldehydes and acyl phosphonates control these two different pathways.
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