Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 25, Pages 9727-9729Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja204228q
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Funding
- National Institute of General Medical Sciences [GM-43854]
- Lilly Graduate Research Fellowship
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The synthesis of the potent molluscicide cyanolide A has been achieved in 10 steps without the use of protecting groups. The synthesis features a key Sakurai macrocyclization/dimerization reaction that simultaneously forms both tetrahydropyran rings and the macrocycle of the natural product.
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