4.8 Article

Gated Photochromism in Triarylborane-Containing Dithienylethenes: A New Approach to a Lock-Unlock System

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 49, Pages 19622-19625

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja208097a

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Funding

  1. University of Hong Kong
  2. URC
  3. University Grants Committee [AoE/P-03/08]
  4. Hong Kong UGC [SEG HKU09]

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Photochromic inactive dithienylethene derivatives appended with 3- or 5-dimesityiboryl-2,2'-bithiophene have been synthesized. Upon fluoride ion-binding, the photochromic reactivity is unlocked, displaying a novel gated photochromic property.

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