Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 11, Pages 3736-3739Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1106767
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Funding
- NSFC [50803072, 50821062]
- 973 Project [2009AA033601]
- CAS [2007CB936400]
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Patterned bead in pore composite film with hemispherical or mushroomlike TiO2 microparticles lying in the holes of a honeycomblike polystyrene matrix has been fabricated by a template-free bottom-up approach from a homogeneous solution of TiCl4/polystyrene/CHCl3 using the breath figures method. It is a very simple way to prepare hemispherical or mushroomlike TiO2 microparticles and to get the hexagonally nonclose-packed arrays of asymmetrical particles with or without polymer matrix, which have potential applications in photonics.
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