Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 5, Pages 1228-1231Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja109191z
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Funding
- National Science Foundation [DMR-0906815, DMR-1032267]
- McDonnell International Scholars Academy
- Welch Foundation
- W. T. Doherty-Welch Chair in Chemistry [A-0001]
- NIH [P30 DC004665]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0906815, 1032267] Funding Source: National Science Foundation
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We have developed a hierarchical process that combines linear triblock copolymers into concentric globular subunits through strong chemical bonds and is followed by their supramolecular assembly via weak noncovalent interactions to afford one-dimensionally assembled, dynamic cylindrical nanostructures. The molecular brush architecture forces triblock copolymers to adopt intramolecular interactions within confined frameworks and then drives their intermolecular interactions in the mixtures of organic solvent and water. In contrast, the triblock copolymers, when not preconnected into the molecular brush architectures, organize only into globular assemblies.
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