Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 36, Pages 14252-14255Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2066219
Keywords
-
Categories
Funding
- National Science Foundation [CHE0845063, CHE0923236]
- Amgen Inc.
- Dow Chemical Company
- Northwestern University
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0923236] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [845063] Funding Source: National Science Foundation
Ask authors/readers for more resources
The development of an efficient oxidative [2,3]-sigmatropic rearrangement of allylic hydrazides, via singlet N-nitrene intermediates, is reported. The requisite allylic hydrazide precursors are readily prepared and undergo smooth sigmatropic rearrangement upon exposure to iodosobenzene. The products of this novel transformation are shown to be useful precursors to a variety of compounds.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available