Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 35, Pages 13782-13785Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja206050b
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Funding
- NIHGMS [R01 GM078201-05]
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The enantioselective alpha-arylation of both lactones and acyl oxazolidones has been accomplished using a combination of diaryliodonium salts and copper catalysis. These mild catalytic conditions provide a new strategy for the enantioselective construction and retention of enolizable alpha-carbonyl benzylic stereocenters, a valuable synthon for the production of medicinal agents.
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