4.8 Article

Polymorphism and Reversible Mechanochromic Luminescence for Solid-State Difluoroboron Avobenzone

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 7, Pages 2160-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja9097719

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Funding

  1. National Science Foundation [CHE 0718879]

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Difluoroboron avobenzone (BF(2)AVB), a simple boron complex of a commercial sunscreen product, exhibits morphology-dependent emission and mechanochromic the solid state. When scratched. smeared, or even gently touched, the emission color of BF(2)AVB films is significantly red-shifted Under UV excitation. In the rubbed regions, the florescence recovers slowly at room temperature Or much Faster with heating, resulting in a simple rewritable scratch the surface ink of potential commercial use.

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