4.8 Article

Probing the Magnetic Properties of Three Interconvertible Redox States of a Single-Molecule Magnet with Magnetic Circular Dichroism Spectroscopy

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 6, Pages 1756-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja9095895

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Funding

  1. Marie Curie EST FuMaSSEC
  2. EU NOE MAGMANet [515767-2]
  3. EMOCIONA [CTQ2006-06333/BQU]
  4. CIBER de Bioingenteria
  5. Biomateriales y Nanomedicina (CIBER-BBN, promoted by ISCIII), Spain

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The hysteresis of magnetization of the anionic, neutral, and cationic forms of a bis(phthalocyaninato)terbium-based complex ([Pc(2)Tb](-/0/+) have been determined Using magnetic circular dichroism (MCD) spectroscopy In frozen dilute solutions at low temperatures (1.5 K) showing that the three oxidation states of the complex exhibit single-molecule magnetic behaviors.

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