Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 34, Pages 11881-11883Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja104743k
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Funding
- MICINN [CTQ2010-16088/BQU, CSD2006-0003]
- AGAUR [SGR 47]
- ICIQ Foundation
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The gold(I)-catalyzed cyclization of 1-(prop-2-yn-1-yl)-2-alkenylbenzenes substituted at the benzylic position with OR groups gives 1,3-disubstituted naphthalenes with concomitant fragmentation of the alkene. One of these annulations proceeds by a retro-cyclopropanation that leads to free gold(I) carbenes.
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