Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 40, Pages 14092-14103Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1036644
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Funding
- NSF [CHE-0952753]
- NIH-NIGMS [GM088237]
- ARO-DURIP
- ONR-DURIP
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0952753] Funding Source: National Science Foundation
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In 2009, we reported C halogen reductive elimination reactions from dinuclear Pd(III) complexes and implicated dinuclear intermediates in Pd(OAc)(2)-catalyzed C-H oxidation chemistry. Herein, we report results of a thorough experimental and theoretical investigation of the mechanism of reductive elimination from such dinuclear Pd(III) complexes, which establish the role of each metal during reductive elimination. Our results implicate reductive elimination from a complex in which the dinuclear core is intact and suggest that redox synergy between the two metals is responsible for the facile reductive elimination reactions observed.
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