4.8 Article

PbTiO3 Nanofibers with Edge-Shared TiO6 Octahedra

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 16, Pages 5572-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja1011614

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Funding

  1. National Science Foundation of China [50452003]
  2. China Postdoctoral Science Foundation [20090451436]

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A new tetragonal phase of PbTiO3 was discovered, in which each TiO6 octahedron pair shares an edge and stacks over following pairs in an interlaced manner to form a one-dimensional (1D) columned structure along the c-axis. This new tetragonal phase of PbTiO3 transforms into a normal perovskite phase in air at elevated temperature.

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