Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 30, Pages 10262-10263Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1046846
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Funding
- NSF [CHE-0924410]
- DFG
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0924410] Funding Source: National Science Foundation
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One-electron oxidation of a readily available phosphaalkene derived from a cyclic (alkyl)(amino)carbene affords a phosphorus-centered radical cation that is indefinitely stable both in solution and in the solid state, allowing a single X-ray diffraction study to be performed. This species can be regarded as a phosphinyl radical bearing a cationic substituent or, alternatively, as a carbene-stabilized phospheniumyl radical (carbene-RP+center dot).
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