Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 39, Pages 13645-13647Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1058229
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Funding
- National Natural Science Foundation of China [20935001]
- Tianjin Natural Science Foundation [10JCZDJC16300]
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A zeolitic imidazolate framework-8 (ZIF-8) nanocrystal coated capillary is shown not only to have a strong ability to sieve branched alkanes from linear alkane isomers owing to the narrow pore windows but also to offer excellent features for high-resolution gas chromatographic separation of linear alkanes due to van der Waals interaction between linear alkanes and the hydrophobic inner surfaces of the micropores. This makes the ZIF-8 coated capillary very promising for the specific adsorption and separation of alkanes in complicated matrices.
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