Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 23, Pages 7848-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1024436
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- U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy
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We report a unique synthesis of core/shell Pd/FePt nanoparticles (NPs) and their catalysis of the oxygen reduction reaction (ORR). The uniform FePt shell is formed by controlled nucleation of Fe(CO)(5) in the presence of a Pt salt and Pd NPs at designated reaction temperatures. The Pd/FePt NPs show FePt shell-dependent catalytic properties, and those having a 1 nm FePt shell exhibit a drastic increase in durability and activity (15 times more active with a 140 mV gain in onset potential in comparison with those having a 3 nm coating). These Pd/FePt NPs are promising new catalysts for practical fuel cell applications.
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