Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 37, Pages 13008-13015Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105340b
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Funding
- NSF of China [20825311, 20773026, 20721063]
- Science and Technology Commission of Shanghai Municipality [08DZ2270500, 09ZR1401900]
- Shanghai Institute of Higher Learning
- Special Funds for Major State Basic Research Projects of China [2005CB321700]
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Due to its high overpotential and low efficiency, the conversion of water to O-2 using solar energy remains a bottleneck for photocatalytic water splitting. Here the microscopic mechanisms of the oxygen evolution reaction (OER) on differently structured anatase surfaces in aqueous surroundings, namely, (101), (001), and (102), are determined and compared systematically by combining first-principles density functional theory calculations and a parallel periodic continuum solvation model. We show that OER involves the sequential removal of protons from surface oxidative species, forming surface peroxo and superoxo intermediates. The initiating step, the first proton removal, dictates the high overpotential. Only at an overpotential of 0.7 V (1.93 V vs SHE) does this rate-controlling step become surmountable at room temperature: the free energy change of the step is 0.69, 0.63, and 0.61 eV for (101), (102), and (001) surfaces, respectively. We therefore conclude that (i) OER is not sensitive to the local surface structure of anatase and (ii) visible light (
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