Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 33, Pages 11420-11421Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105767z
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Funding
- MEXT, Japan [21750099, 20350049]
- Uehara Memorial Foundation
- Iketani Science and Technology Foundation
- Kyoto University
- Grants-in-Aid for Scientific Research [21750099, 20350049] Funding Source: KAKEN
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Dehydrohalogenative polycondensation of 2-bromo-3-hexylthiophene was successful with Herrmann's catalyst and tris(2-dimethylaminophenyl)phosphine as catalyst precursors, giving head-to-tail poly(3-hexylthiophene) (HT-P3HT) with high molecular weight (M-n = 30 600, M-w/M-n = 1.60) and high regioregularity (98%) in almost quantitative yield (99%).
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