Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 49, Pages 17370-17373Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja108642s
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Funding
- Max-Planck-Society
- DFG [SPP1179]
- Fonds der Chemischen Industrie
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The highly enantioselective kinetic resolution of homoaldols via a transacetalization reaction has been achieved. A novel phosphoric acid, STRIP, based on a spirocyclic 1,1'-spirobiindane backbone was designed and identified as a superior catalyst for this transformation. Remarkably, both secondary and tertiary homoaldols gave equally excellent results.
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