Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 24, Pages 8506-8512Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1030968
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Funding
- National Institutes of Health [HL25848]
- National Science Foundation [CHE-0619638]
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An appropriately constructed 2-substituted derivative of L-tryptophan undergoes conversion to a prephalarine structure in a single step. The reaction occurs in a diastereoselective fashion, leading shortly thereafter to the naturally occurring version of the alkaloid phalarine.
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