4.8 Article

Dual Redox Responsive Assemblies Formed from Diselenide Block Copolymers

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 2, Pages 442-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja908124g

Keywords

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Funding

  1. National Basic Research Program [2007CB808000]
  2. National Natural Science Foundation of China [20944001, 20904028, 50973051, 20974059]
  3. Science Foundation of China Postdoctor [20080440362]
  4. NSFC-DFG [TRR 61]

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A block copolymer with diselenide bonds in the polymer backbone was reported. This block copolymer was capable of forming micellar aggregates that were responsive to redox stimuli. Compared with other redox responsive aggregates, this type of diselenide-containing block copolymer aggregates Could be responsive to both oxidants and reductants even in a solution with a very low concentration under mild conditions.

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