Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 26, Pages 8858-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja103429q
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Funding
- EPSRC
- ERC (FUNCAT)
- Engineering and Physical Sciences Research Council [EP/H015418/1] Funding Source: researchfish
- EPSRC [EP/H015418/1] Funding Source: UKRI
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A highly efficient [(NHC)Au-1]-based (NHC = N-heterocyclic carbene) catalytic system for the carboxylation of aromatic and heteroaromatic C-H bonds was developed. The significant base strength of the Au-OH species is at the origin of the activation process and permits the facile functionalization of C-H bonds without the use of other organometallic reagents.
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