4.8 Article

A Metal-Organic Framework with a Covalently Prefabricated Porous Organic Linker

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 37, Pages 12773-12775

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja104083y

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Funding

  1. Engineering and Physical Sciences Research Council (EPSRC) [EPSRC/C511794]
  2. Royal Society
  3. Engineering and Physical Sciences Research Council [EP/C511794/1, EP/H000925/1] Funding Source: researchfish
  4. EPSRC [EP/H000925/1] Funding Source: UKRI

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We report here the synthesis of a metal organic framework comprising an organic cage linker with covalently prefabricated, intrinsic porosity. The network can be compared to a porous rock salt structure where the pores are partially filled by charge-balancing cations.

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