Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 38, Pages 13123-13125Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1041513
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Funding
- Department of Energy [DE-FG02-02ER45999]
- NSF [NSF 9974899, CHE 0079822]
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To expand the field of new cyanide materials of the 5d elements, we incorporated the [Os(CN)(6)](3-) anion into PB architectures in combination with the Co-II cation. Herein, we report the first example of a photomagnetic PB analog containing Os-III ions. In a similar vein as the prototypical CoFe PB analogs, this compound exhibits a wide variety of properties including Charge Transfer Induced Spin Transition (CTIST), Temperature Induced Excited Spin State Trapping (TIESST), and magnetic ordering.
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