4.8 Article

Gold(I)-Catalyzed Intermolecular [2+2] Cycloaddition of Alkynes with Alkenes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 27, Pages 9292-9294

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja104177w

Keywords

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Funding

  1. MICINN [CTQ2007-60745/BQU, CSD2006-0003]
  2. MEC
  3. AGAUR [2009 SGR 47]
  4. ICIQ Foundation

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The gold(I)-catalyzed intermolecular reaction of terminal alkynes with alkenes leads to cyclobutenes. The use of sterically hindered cationic Au(I) complexes as catalysts is key for the success of this reaction.

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