Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 25, Pages 8554-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja103078q
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Funding
- National Science Foundation [CHE-0555696, CHE-0848511, DEG-0806677-004]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0848511] Funding Source: National Science Foundation
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In this communication we provide the first UHV-STM images and STM-based current-voltage (I-V) and orbital mediated tunneling spectroscopy (OMTS) data on a self-assembled porphyrin nanostructure at the single structure level. We will show that transverse conductivity over distances less than 10 nm can occur by barrier type tunneling but that long distance conduction solely occurs through the LUMO band. These nanorods are very highly rectifying.
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