Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 4, Pages 1202-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja907982w
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- National Science Foundation
- Research Corporation for Science Advancement
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A copper-promoted coupling of vinyl pinacol boronate esters and alcohols for the synthesis of enol ethers is reported. The reaction occurs In 50-99% yield and is compatible with a variety of functional groups. Cupric acetate is the copper Source, and triethylamine buffer is used to prevent protodeboration; the reaction occurs at room temperature. In addition to excellent chemoselectivity, the reaction is stereospecific.
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