4.8 Article

Photoswitchable Catalysis Mediated by Dynamic Aggregation of Nanoparticles

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 32, Pages 11018-11020

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja104260n

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Funding

  1. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0000989]

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Catalytic activity of gold nanoparticles in a hydrosilylation reaction is controlled by irradiation with UV or visible light. When exposed to UV, the particles aggregate and the catalysis is effectively switched off'. When the particles are exposed to visible light, the particles redisperse and catalysis can proceed.

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