Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 42, Pages 14754-14756Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja107444m
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Funding
- Association for the Progress of New Chemistry
- KAKENHI [20750097]
- Grants-in-Aid for Scientific Research [20750097] Funding Source: KAKEN
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Herein, we report on a self-threading polythiophene whose conjugated molecular wire is sheathed within its own cyclic side chains. The defect-free insulating layer prevents electronic cross-communication between the adjacent polythiophene backbone even in the solid film. Notably, the covalently linked cyclic side chains extend the effective conjugation length of the interior polythiophene backbone, which results in an excellent intrawire hole mobility of 0.9 cm(2) V-1 s(-1).
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