Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 26, Pages 8885-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1034123
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Funding
- NIHGMS [RO1 GM073932]
- Amgen
- Novartis
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The three-component coupling of terminal alkenes with arylboronic acids and oxygen nucleophiles is described. The reaction employs a binuclear gold(I) bromide as a catalyst and Selectfluor reagent as the stoichiometric oxidant. Alcohols, carboxylic acids, and water can be employed as oxygen nucleophiles, thus providing an efficient entry into B-aryl ethers, esters, and alcohols from alkenes.
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