Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 34, Pages 11917-11919Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105271z
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A stereospecific allylic amination of unactivated secondary (2 degrees)-allylic alcohols is reported. The primary (1 degrees)-allylic amine can be isolated directly or protected in situ. Spectroscopic studies have shed light on the structure of the catalytically active Ir.(P,olefin)2I complex.
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