Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 47, Pages 16745-16746Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja108907x
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Funding
- 973 Program [2010CB833201]
- National Science and Technology Major Project [2009ZX09501-012]
- National Science Foundation of China [20821062, 20832003, 20902007]
- Shenzhen Basic Research Program [JC200903160352A]
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A concise first total synthesis of (+/-) maoecrystal V (1) is reported. The synthesis features a Wessely oxidative dearomatization of a phenol, an intramolecular Diels-Alder reaction, and a Rh-catalyzed O-H bond insertion as key steps.
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