Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 41, Pages 14334-14335Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105768w
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Funding
- DFG
- Fonds der Chemischen Industrie
- RD IFSC (Ruhr-University Bochum)
- Int. Max Planck Research School in Chemical Biology
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Two series of selectively deuterated cryptates with the lanthanoids Yb and Nd have been synthesized, and the luminescence lifetimes for the corresponding near-IR emission bands have been measured. Global fitting of these lifetime data combined with structural analysis allows for the accurate quantification of the contributions of individual C-H oscillators groups in the ligand to the nonradiative deactivation rates of the emissive lanthanoid states.
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