4.8 Article

High Proton Conductivity in Prussian Blue Analogues and the Interference Effect by Magnetic Ordering

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 19, Pages 6620-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja100385f

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Funding

  1. JSPS
  2. MEXT, Japan
  3. Izumi Foundation
  4. Asahi Glass Foundation

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We observed high proton conductivities of 1.2 x 10(-3) and 1.6 x 10(-3) S cm(-1) on Co[Cr(CN)(6)](2/3)center dot zH(2)O and V[Cr(CN)(6)](2/3)center dot zH(2)O, respectively, and an interference effect between magnetic ordering and ionic conduction below the magnetic phase transition temperature.

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