4.8 Article

Cubic Octanuclear Ni(II) Clusters in Highly Porous Polypyrazolyl-Based Materials

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 23, Pages 7902-7904

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja102862j

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Funding

  1. Fondazione CARIPLO [20075117]

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Two highly porous coordination polymers, containing rare octanuclear hydroxo-nickel clusters and long bis-pyrazolyl spacers, are shown to possess, after mild thermal treatment, lattice cavities up to 72% of the total crystal volume.

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