Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 17, Pages 5962-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja101673v
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Funding
- NIH/NIGMS [R01 GM077379]
- Eli Lilly
- Amgen
- Tobacco-Related Disease Research Program
- Japan Society for the Promotion of Science (JSPS)
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A hydroxyl group-directed, highly regio- and stereoselective transposition of allylic alcohols based on rhenium catalysis has been developed. The method is suitable for a direct isomerization of acetals into the thermodynamically preferred isomer as long as one of the hydroxyl groups is allylic. This method will expand the scope of rhenium-catalyzed alcohol transpositions for complex molecule synthesis.
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