Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 3, Pages 924-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9095413
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- NanoCat
- International Graduate Program within the Elitenetzwerk Bayern
- Graduiertenstipendium nach dem Bayerischen Eliteforderungsgesetz
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A novel Catalytic C-C coupling reaction in which N-heteroaromatic-substituted methyl groups are efficiently alkylated using, primary alcohols is introduced. The synthesis protocol is based on iridium catalysts and most likely relies on the borrowing hydrogen or hydrogen autotransfer mechanism. A variety Of substrate combinations can readily be employed in this reaction, including pyrimidines, pyridazines, and even fairly activated 2- and 4-picolines.
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